Follow the directions in this post to print a document from Microsoft Word 2010.
1) Open the document you want to print in Microsoft Word 2010 (if the document is not already open).
2) Click the blue “File” tab at the top
3) Click the “Print” option from the left menu
4) If you need to, select the printer that you want to print your document to from the “Printer” drop down list.
5) Click the large “Print” icon to send your document to the printer